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Ninova
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Fen-Edebiyat Fakültesi
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KIM 311E
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Hafta
Konu
1
17 September; Introduction: Summary of Thermodynamics (0th, 1st,2nd and 3rd laws). Reminding basic concepts.
2
24 September; Variation of Gibbs Free Energy with pressure and temperature : Single and Multi-component systems. Chemical potential.
3
1 October; State Functions: Virial Expansions and fugacity. Chapter exercises.
4
8 October; Gibbs phase rule. Phase diagrams of single component system. The location of phase boundaries.
5
15 October; Clapeyron and Clasius-Clapeyron Equations. First and Second order phase transitions. Phase diagram of pure substances. Chapter Exercises.
6
22 October; Simple Mixtures: Partial Molar quantities. Gibbs – Duhem Equation. Enthalpy, entropy and Gibbs energy of mixtures.
7
29 October; National Holiday – Republic Day
8
5-9 November; Break
9
12 November; Ideal and Ideal-dilute solutions: Roult’s law and Henry’s Laws. Thermodynamics of real solutions. Ideal solubility.
10
19 November; Colligative properties: The elevation of boiling point, the depression of freezing point, vapor pressure and osmotic pressure, Activity and activity coefficient. Chapter exercises.
11
26 November; Phase diagrams of two-component systems. P-X and T-X diagrams of miscible mixtures.
12
3 December; Distillation of azeotrope, partially miscible and immiscible liquid-liquid systems. Solid-liquid phase diagrams of solid-solid systems. Composite phase diagrams, ultra purity and controlled impurity.
13
10 December; Reaction Gibbs Free Energy, The composition of reactions at equilibrium
14
17 December; Effect of temperature and pressure on equilibrium, van’t Hoff equation.
15
24 December; Thermodynamics and electromotive force, Gibbs-Helmholtz equation and Nernst Equation.
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