KIM 473E - Organik Yapı Analizi

Dersin Amaçları

Course Description
1. Short introduction to organic structure analysis. Elemental analysis. 2. UV Spectroscopy: Chromophore and auxochrome groups, electronic transitions, several examples from conjugated olefins, carbonyl compounds and aromatics. 3. IR Spectroscopy: Bond vibrational levels and functional groups, vibrational modes, CH, OH and NH bands, bands of major sp and sp2 hybridized functions, C-O and C-N bands. 4. Mass Spectrometry: Fragmentation patterns of molecules, effect of isotopes, determination of the molecular mass. 5. NMR Spectroscopy: Nuclear spin and classification of nuclei, behavior in external magnetic field, basic concepts, chemical shift and its reasons, effect of alkyl groups, multiple bonds and magnetic anisotropy, spin-spin coupling and J values, long- range couplings, 1H and 13C NMR and examples for various chemical shifts and coupling constants.

Dersin Tanımı

Course Description
1. Short introduction to organic structure analysis. Elemental analysis. 2. UV Spectroscopy: Chromophore and auxochrome groups, electronic transitions, several examples from conjugated olefins, carbonyl compounds and aromatics. 3. IR Spectroscopy: Bond vibrational levels and functional groups, vibrational modes, CH, OH and NH bands, bands of major sp and sp2 hybridized functions, C-O and C-N bands. 4. Mass Spectrometry: Fragmentation patterns of molecules, effect of isotopes, determination of the molecular mass. 5. NMR Spectroscopy: Nuclear spin and classification of nuclei, behavior in external magnetic field, basic concepts, chemical shift and its reasons, effect of alkyl groups, multiple bonds and magnetic anisotropy, spin-spin coupling and J values, long- range couplings, 1H and 13C NMR and examples for various chemical shifts and coupling constants.