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Course Weekly Lecture Plan

Week Topic
1 1- Definition of free radicals, properties, stabilities, reactivities and kinetics
2 2- Radicals centered on an atom other than carbon
3 3-Reactions and mechanisms of free radicals I (production methods of free radicals, radical-radical reactions, substitution reactions)
4 4-Reactions and mechanisms of free radicals II (production methods of free radicals, radical-radical reactions, substitution reactions)
5 5-Reactions and mechanisms of free radicals III (addition and fragmentation reactions of free radicals)
6 6-Reactions and mechanisms of free radicals IV (cyclizations and rearrangement reactions of radicals)
7 7-Aromatic substitution reactions of free radicals
8 8-Reactions of charged radicals and free radicals in biochemistry
9 9-How to prove that a reaction is a radical process
10 10-Applications in synthesis I (functionalization of C-H bond, transformation of functional groups, additions of multiple bonds and coupling reactions)
11 11-Applications in synthesis II (Reaction of Barton-McCombie for nucleosides and sugars, Barton Decarboxylation reaction, free radical reactions with metal hydride)
12 12-Applications in polymer chemistry (free radical polymerization) I
13 13-Applications in polymer chemistry (controlled/living radical polymerization) II
14 14-Current advances
 
 
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